(Van ‘t Hoff Laboratory for Physical and Colloid Chemistry, Utrecht - Lekkerkerker) Hexagonal gibbsite platelets Gibbsite Particle size: 150 - 225 nm diameter, 7 - 10 nm thick up to 600 nm diameter in seeded growth, 40 nm thick Surface properties: Charge stabilized in water Sterically stabilized in toluene (covered with PIB) Solvent: H2O, toluene Typical concentration after preparation: 5 - 8 g/L Typical time needed to prepare: 3 weeks References: Kooij, F. van der et al., J. Phys. Chem. B, 102, (1998), 7829-7832 Wijnhoven, J.E.G.J., J. Colloid Interf. Sci., (2005), accepted for publication |   | Gibbsite covered with silica Particle size: SiO2 layer thickness 4 – 30 nm Surface properties: Charge stabilized Solvent: Mixture of ethanol, water and ammonia Typical concentration after preparation: 1 g/L Typical time needed to prepare: 3 days (starting from bare gibbsite) References: Wijnhoven J.E.G.J., Chem. Mater., 16, (2004), 3821-3828 |   | Fluorescent gibbsite Particle size: Dyed layer thickness 7 – 30 nm Surface properties: Charge stabilized Solvent: Mixture of ethanol, water and ammonia or DMF Typical concentration after preparation: 1 g/L Typical time needed to prepare: 5 days (starting from bare gibbsite) References: Vonk, C. et al., J. Colloid Interf. Sci., 278, (2005), 521-525 |   | |