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Gibbsite Platelets
(Van ‘t Hoff Laboratory for Physical and Colloid Chemistry, Utrecht - Lekkerkerker)


Hexagonal gibbsite platelets

Gibbsite

Particle size:
150 - 225 nm diameter, 7 - 10 nm thick up to 600 nm diameter in seeded growth, 40 nm thick

Surface properties:
Charge stabilized in water Sterically stabilized in toluene (covered with PIB)

Solvent:
H2O, toluene

Typical concentration after preparation:
5 - 8 g/L

Typical time needed to prepare:

3 weeks

References:
Kooij, F. van der et al., J. Phys.
Chem. B, 102, (1998), 7829-7832
Wijnhoven, J.E.G.J., J. Colloid
Interf. Sci., (2005), accepted for publication
Gibbsite 500nm 1

Gibbsite 500 nm 2


Gibbsite covered with silica

Particle size:
SiO2 layer thickness 4 – 30 nm

Surface properties:
Charge stabilized

Solvent:
Mixture of ethanol, water and ammonia

Typical concentration after preparation:
1 g/L

Typical time needed to prepare:
3 days (starting from bare gibbsite)

References:
Wijnhoven J.E.G.J., Chem.
Mater., 16, (2004), 3821-3828
Gibbsite covered with silica 100 nm 1

Gibbsite covered with silica 100nm 2


Fluorescent gibbsite

Particle size:
Dyed layer thickness 7 – 30 nm

Surface properties:
Charge stabilized

Solvent:
Mixture of ethanol, water and ammonia or DMF

Typical concentration after preparation:
1 g/L

Typical time needed to prepare:
5 days (starting from bare gibbsite)

References:
Vonk, C. et al., J. Colloid Interf.
Sci., 278, (2005), 521-525
Fluorescent gibbsite 1

Fluorescent gibbsite 2
Last modified: 22/02/2008